Chapter 5.  Energy Conservation in Photosynthesis:  CO2 Assimilation

  • More about stomata:
    • Table 5.1 show typical density and distribution of stomata.  The range is about 20-400/mm2.
    • Pores occupy 0.2-2% of surface area, but diffusion through pores is very efficient and may be equivalent to rate expected from 70% of surface area.
  • Guard cell movement in brief: due to orientation of cellulose microfibrils in guard cells, when guard cells take up water and become turgid, they expand asymmetrically.  This opens the stoma. See Figure 5.5.
  • Now for the details:
    • Uptake of water is due to increase in guard cell water potential, this in turn is due to accumulation of K+, Cl- and malate ions in vacuole.
    • An ATP-ase proton pump produces proton efflux.  This results in passive uptake of K+ and cotransport of Cl-.  Malate is produced by hydrolysis of starch.  See Figure 5.6.
    • Environmental cues:
      • Low CO2 content in substomatal cavity triggers opening.
      • Light, especially blue light, triggers opening.  Specific blue light receptors are involved.
      • Drought stress triggers closure:
        • Hydropassive closure - guard cells lose water,  become flaccid.
        • Hydroactive closure - plant senses water deficit, stomata close.  The hormone ABA is involved, and water deficit can be sensed in leaves or roots.
    • All these processes require complex signal transduction pathways, ending with activation of the proton pumps.

·        PCR (Calvin) Cycle - review

    • Carboxylation of C5 sugar to produce unstable C6 compound, dissociates to C3 compound, PGA.
    • Reduction of C3 compound to C3 sugar (a triose, G3P).  This process consumes ATP and NADPH (from the light dependent reaction).
    • Some of the triose is exported, the rest is used to regenerate C5 compound.
    • This is C3 metabolism and is universal in photosynthetic cells.
    • This process is illustrated in more detail in Figures 5.9,10,11.
  • Photorespiration
    • Respiration in the sense that is an O2-consuming and CO2-generating process.  There is no net gain of ATP.
    • Due to oxygenase function of Rubisco.
    • C5 compound oxidized, some of the carbon lost as CO2.  Regeneration of C5 requires ATP.  This is the glycolate cycle.
    • Why?  Some hypotheses:
      • "Oxygenase function of Rubisco is inescapable".  This is a vestigial trait, an echo of the Precambrian world with an atmosphere low in oxygen.
      • The glycolate cycel produces useful compounds (e.g. amino acids) as intermediates.
      • Photorespiration can dissipate excessive excitation energy when light is present but CO2 isn't (closed stomata).
  • C4 and CAM pathways may be ways of compensating for wasteful nature of photorespiration.
  • C4 cycle
    • Uses PEPcase to capture CO2.
    • C1 (CO2) + C3 (PEP) makes C4 (e.g. malate), hence the term.
    • C4 is decarboxylated, CO2 is passed to the Calvin cycle.
    • Benefits:
      • PEPcase has a higher affinity for CO2 than Rubisco, can scavenge CO2 at low concentration when stomata are closed (or nearly so) to conserve H2O.
      • PEPcase is more heat tolerant than Rubisco
      • Physical separation of carboxylation (in mesophyll) and carbon reduction (in bundle sheath) pathways inhibits photorespiration.
    • Ecology of C4 metabolism
      • Has independently evolved in many plant families, but most common in desert and tropical species.
      • High water use efficiency that C3 plants.
      • Better able to exploit high light intensities.
  • CAM, Crassulacean Acid Metabolism
    • CAM plants (typically desert succulents) use the C4 pathway but separate carbon fixation and carbon reduction in time, not space.
    • During the night: stomata open, CO2 diffuses in, C4 pathway fixes carbon in C4 acids.
    • Sunrise: stomata close to reduce water loss.
    • During the day: light dependent reactions turn on, resulting  ATP and NADPH used by PCR (Calvin) cycle to make sugar.
  • CAM and C4 metabolism are illustrated in Figures 5.22,23,26.